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Structure of isostructural lanthanide-oxalate frameworks comprising eight kinds of lanthanide ions and oxalate and its strontium adsorbed structure

dataset
posted on 2024-05-17, 02:35 authored by Takuya Nankawa, Yurina SEKINE, Teppei Yamada

These CIF files contain the structural information for a series of lanthanide-oxalate frameworks, LOF-Ln-NH4 (NH4[Ln(ox)2]-H2O, (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, or Tm, ox = oxalate)) and LOF-Tb-Sr (Sr0.5[Tb(ox) 2・6H2O]), determined by the single crystal X-ray diffraction. These structures were solved by a direct method and expanded using Fourier techniques.Full-matrix least-squares refinements were carried out using SHELX-97.

Funding

Development of element-selective separation technology utilizing sub-angstrom level micropore control

Japan Society for the Promotion of Science

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Elucidation of specific adsorption mechanism of bone-derived nanoapatite and development of selective removal and disposal technology of radioactive substances

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Matal organic framework capable of separating and recovering ions from nuclear liquid waste

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History

Corresponding author email address

nankawa.takuya@jaea.go.jp

Title (in Japanese)

シュウ酸イオンと8種類のランタノイドイオンからなるランタノイド-シュウ酸フレームワークの構造とそのストロンチウム吸着構造

Description (in Japanese)

これらのCIFファイルは、シュウ酸塩と8種類のランタニド(Ln)イオンからなる一連のランタニド-シュウ酸塩骨格 LOF-Ln-NH4 (NH4[Ln(ox)2]-H2O (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, or Tm, ox:シュウ酸塩)) 及びLOF-Tb-Sr (Sr0.5[Tb(ox) 2・6H2O])について、単結晶X線構造回折法により決定した構造を示したものである。結晶構造は直接法とフーリエ法によって解析され、最小二乗法による精密化はSHELX-97を用いて行われた。

Manuscript title (in Japanese)

SrとCaを分離可能なランタノイドシュウ酸フレームワークによるサブオングストローム細孔径制御とイオン選択的分離回収

Authors (in Japanese)

南川 卓也,関根 由莉奈,山田 鉄兵

Copyright

© 2024 Atomic Energy Society of Japan

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    日本原子力学会和文論文誌/Transactions of the Atomic Energy Society of Japan

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