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Mechanochemical Synthesis of KxMn[Fe(CN)6] and CNT Composite for High-power Potassium-ion Batteries (Supporting Information)

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posted on 2024-01-24, 00:46 authored by Tomooki HOSAKA, Nobuhito NORO, Shinichi KOMABA

This study introduces a facile mechanochemical synthesis of KxMn[Fe(CN)6] (KMnHCF) and carbon nanotube (CNT) composite (KMnHCF@CNT) as a positive electrode material for potassium-ion batteries. The KMnHCF@CNT, synthesized by a simultaneous process of mechanochemical synthesis and carbon compositing, shows a homogeneous composite and achieves a much higher electron conductivity of 7.16 × 10−1 S cm−1 than the KMnHCF and CNT mixture (2.35 × 10−2 S cm−1) synthesized by the two-step process. The improved electron conductivity demonstrates reduced carbon content in the electrode and excellent rate performance of maintaining 80 mAh g−1 at 20 C in potassium cells.

Funding

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Agency

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History

Corresponding author email address

komaba@rs.tus.ac.jp

Copyright

© 2024 The Author(s).

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