Mechanistic Insights into Electrooxidative Allylation of a Carbamate in the Presence of Solid-Supported Acids (Supporting Information)

<div>The electrooxidative allylation of a carbamate was successfully demonstrated using 3-propylsulfonic acid-functionalized silica gel (Si-SCX-2). It was shown that the electrochemical oxidation of the carbamate as a first step yields the corresponding <i>N</i>-acyliminium ion equivalent at room temperature, and the reaction of the <i>N</i>-acyliminium ion equivalent with allyltrimethylsilane as a next step leads to allylation without the use of Lewis acids. It was also found that the HBF₄ generated by the cation exchange reaction between the Si-SCX-2 and the supporting electrolyte plays an important role in this reaction system.</div>