Effects of Ion Fraction in an Inorganic Ionic Liquid Electrolyte on Performance of Intermediate-Temperature Operating Sodium-Sulfur Batteries (Supporting Information)
<p>Sodium-sulfur (Na-S) batteries are promising energy storage systems for renewable energy sources which redeem an intermittent energy source. This study reports the effects of the Na[SO<sub>3</sub>CF<sub>3</sub>] fraction in an inorganic Na[SO<sub>3</sub>CF<sub>3</sub>]-Cs[N(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub>] ionic liquid electrolyte (<i>x</i>(Na[SO<sub>3</sub>CF<sub>3</sub>]) = 0.2, 0.3, and 0.4) on the performance of Na-S batteries. Measurements of physicochemical and electrochemical properties demonstrated that decrease in the Na[SO<sub>3</sub>CF<sub>3</sub>] fraction decreases viscosity and increases ionic conductivity and the solubility of polysulfides into the ionic liquid, which contributes to the enhanced capacity in the low potential region during discharging.</p>
Funding
Liquid sodium metal secondary battery using solid-liquid two-phase electrolyte