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Effects of Ion Fraction in an Inorganic Ionic Liquid Electrolyte on Performance of Intermediate-Temperature Operating Sodium-Sulfur Batteries (Supporting Information)

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posted on 2023-03-30, 07:11 authored by Di WANG, Jinkwang HWANG, Keigo KUBOTA, Kazuhiko MATSUMOTO, Rika Hagiwara
<p>Sodium-sulfur (Na-S) batteries are promising energy storage systems for renewable energy sources which redeem an intermittent energy source. This study reports the effects of the Na[SO<sub>3</sub>CF<sub>3</sub>] fraction in an inorganic Na[SO<sub>3</sub>CF<sub>3</sub>]-Cs[N(SO<sub>2</sub>CF<sub>3</sub>)<sub>2</sub>] ionic liquid electrolyte (<i>x</i>(Na[SO<sub>3</sub>CF<sub>3</sub>]) = 0.2, 0.3, and 0.4) on the performance of Na-S batteries. Measurements of physicochemical and electrochemical properties demonstrated that decrease in the Na[SO<sub>3</sub>CF<sub>3</sub>] fraction decreases viscosity and increases ionic conductivity and the solubility of polysulfides into the ionic liquid, which contributes to the enhanced capacity in the low potential region during discharging.</p>

Funding

Liquid sodium metal secondary battery using solid-liquid two-phase electrolyte

Japan Society for the Promotion of Science

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Corresponding author email address

k-matsumoto@energy.kyoto-u.ac.jp

Copyright

© 2023 The Author(s).

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